F1 - Supramolecular Systems

Rédacteurs: Nicolas Giuseppone, Mario Ruben, Mihail Stadler, Franck Hoonakker, Emilie Moulin, Jean-Marc Planeix, Mourad Elhabiri, (Ali Trabolsi)

C = MxIxI

M: Multiplicity; A/ One single molecule can present several properties e.g. Multiplicity of binding sites, number of energy levels.... B/ Mutiplicity of components: number of components (molecular) /constituents (supramolecular) in the system

I: Interaction A/ Complentaries of shapes, of charges, of energy levels B/ Thermodynamic and kinetic of the interaction (reversibility, lability), covalent / non-covalent bonds C/ Interactions of molecules with their environments (possibly in flux of energies far from equilibrium)

I: Integration

Dynamic In time and space A/ Coformational Dynamic B/ Constitutional dynamic: reversibility of the structure of the systems components C/ Network dynamics in coupled reactions

Bottom-up approach for structuring of hierarchical supramolecular architectures Individual molecules contain a program which code for hierarchical self-assembly

Bottom-up approach for functions design A single system : 1 property A complex system : Multiple properties

Bottom-up construction of molecular networks